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• W2911574343 startingPage "129" @default.
• W2911574343 abstract "Abstract In this review, we classify and analyze the structural data of more than 80 monomeric platinum coordination complexes with an inner coordination sphere of PtP 4 in which only organophosphines are involved. On the basis of the coordination mode of respective organophosphines, these complexes can be divided into six subgroups: Pt(PL) 4 , Pt(PL) 2 (PL′) 2 , Pt(η 2 -P 2 L)(PL) 2 , Pt(η 2 -P 2 L) 2 , Pt(η 2 -P 2 L)(η 2 -P 2 L′) 2 , and Pt(η 4 -P 4 L). The chelating ligands forming wide varieties of metallocycles: (P=P), (PNP), (PCP), (PC 2 P), (PP 2 P), (PC 2 NP), (PNCNP), (PNPNP), (POHOP), (POBOP), (PCNCP), (PC 3 P), (PC 4 P), and (PC 2 OC 2 P). The effects of both steric and electronic factors reflect on the values of P-Pt-P chelate angles. The total mean values of Pt-P elongate in the order: 2.289 Å (tetradentate)<2.306 Å (monodentate)<2.320 Å (bidentate). The same order shows the respective covalent bond weaknesses." @default.
• W2911574343 created "2019-02-21" @default.
• W2911574343 creator A5072525642 @default.
• W2911574343 creator A5075928859 @default.
• W2911574343 date "2019-08-27" @default.
• W2911574343 modified "2023-09-24" @default.
• W2911574343 title "Organophosphines in PtP4 derivatives; structural aspects" @default.
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• W2911574343 doi "https://doi.org/10.1515/revic-2018-0025" @default.
• W2911574343 hasPublicationYear "2019" @default.
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