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• W2911578166 abstract "Sulfur-carbon(sp3) bonds are commonly generated using nucleophilic substitution chemistry. In addition to this methodology, a host of metal and organocatalyzed approaches have been devised and implemented in the syntheses of sulfur-containing compounds. This chapter first highlights some of the developments in this area. Due to sluggish reactivity of aryl and vinyl halides in nucleophilic substitution reactions, the formation of sulfur-carbon(sp2) bonds is typically carried out using transition metal catalysis. While the field is dominated by the use of palladium, copper, and nickel catalysts, considerable advances have been made using more abundant metal catalysts such as iron. Additionally, a number of transition metal-free approaches have been developed for the formation of sulfur-carbon(sp2) bonds. The chapter highlights representative examples of C-S bond forming reactions. The copper-catalyzed coupling of organothiols with vinyl halides remains one of the most efficient approaches to the synthesis of vinyl sulfides." @default.
• W2911578166 created "2019-02-21" @default.
• W2911578166 creator A5041479174 @default.
• W2911578166 date "2016-01-01" @default.
• W2911578166 modified "2023-10-17" @default.
• W2911578166 title "Synthesis of Thioethers, Sulfones, and Related Compounds" @default.
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