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- W2911606247 abstract "Transformation of aromatic azides on the silver surface was studied by atomic force microscopy in ultrahigh vacuum. In their Communication on page 2266, P. Jelínek, I. Starý et al. show that 9-azidophenanthrene decomposes into an elusive nitrenoid intermediate chemisorbed on the surface. It undergoes a formal nitrene insertion into a C−H bond, dimerisation, or hydrogenation to form covalent σ- and π-bonds in the dimeric or reduced products of the on-surface reactions. Transformation of aromatic azides on the silver surface was studied by atomic force microscopy in ultrahigh vacuum. In their Communication on page 2266, P. Jelínek, I. Starý et al. show that 9-azidophenanthrene decomposes into an elusive nitrenoid intermediate chemisorbed on the surface. It undergoes a formal nitrene insertion into a C−H bond, dimerisation, or hydrogenation to form covalent σ- and π-bonds in the dimeric or reduced products of the on-surface reactions. Heterogeneous Catalysis Nitrogen Fixation Self-Assembly" @default.
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- W2911606247 date "2019-01-17" @default.
- W2911606247 modified "2023-09-30" @default.
- W2911606247 title "Cover Picture: Aromatic Azide Transformation on the Ag(111) Surface Studied by Scanning Probe Microscopy (Angew. Chem. Int. Ed. 8/2019)" @default.
- W2911606247 doi "https://doi.org/10.1002/anie.201900409" @default.
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