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- W2911637896 abstract "Understanding the conformation effect on force-induced melting is important for developing advanced semicrystalline polymer materials. Here, two types of polymer single crystals, polycaprolactone (zigzag conformation) and poly(l-lactic acid) (helical conformation), have been selected to study the conformation effect on force-induced melting by using the atomic force microscopy (AFM)-based single-molecule force spectroscopy (SMFS). We find that the zigzag chains facilitate the stick–slip motion, and the single helical chain takes smooth motion during force-induced melting from the single crystals. Furthermore, we illustrate that the conformation acts on the force-induced melting by defining the interaction in between the adjacent stems. This SMFS study deepens our understanding on the relationship between the chain conformation and nanomechanical properties of polymer crystals." @default.
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- W2911637896 date "2019-02-01" @default.
- W2911637896 modified "2023-10-14" @default.
- W2911637896 title "Single-Molecule Force Spectroscopy Study on Force-Induced Melting in Polymer Single Crystals: The Chain Conformation Matters" @default.
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- W2911637896 doi "https://doi.org/10.1021/acs.macromol.8b02702" @default.
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