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- W2911660880 abstract "By utilizing a novel octacarboxylate-functionalized resorcin[4]arene as organic linkers, three lanthanide-coordination polymers, namely, [(CH3)2NH2][Ln2(HL)(H2O)7]·2H2O (Ln = Tb (1), Eu (2) and Gd (3), H8L = 2,8,14,20-tetra-pentyl-4,6,10,12,16,18,22,24-octa-carboxymethoxy-resorcin[4]arene) have been solvothermally synthesized and structurally characterized. Isostructural 1-3 display unique two dimensional sandwich-based layers built with Ln3+ cations and bowl-shaped HL7- anions. Remarkably, 1 and 2 produce intensive green and red emissions respectively and long lifetimes thanks to the antenna effect of HL7- anions. The energy level testing of 3 indicates that the newly designed ligand H8L has a very efficient intersystem crossing process. More importantly, luminescent investigations reveal that 1 and 2 can selectively detect N,N'-dimethylformamide and Fe3+ ions with turn-on-type and turn-off-type responses, respectively." @default.
- W2911660880 created "2019-02-21" @default.
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- W2911660880 date "2019-01-01" @default.
- W2911660880 modified "2023-10-16" @default.
- W2911660880 title "Three resorcin[4]arene-based lanthanide-coordination polymers with multifunctional photoluminescence sensing properties" @default.
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- W2911660880 doi "https://doi.org/10.1039/c8ra09777a" @default.
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