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- W2911902698 abstract "The adsorption and oxidation of CH3OH were studied in 1 M HClO4 on porous Pt and PtxRUy electrodes by means of Differential Electrochemical Mass Spectrometry (DEMS). The electrodes were made by potentiostatic co-deposition on porous Au substrates. It was found that Pt0.9Ru0.1 shows the highest activity compared to pure Pt. For this composition the complete oxidation to CO2 is favoured in contrast to other compositions which yield more amounts of formic acid. The oxidation of poisoning adsorbate species on Pt0.9Ru0.1 is shifted 0.15 V to negative potentials in comparison to Pt. First results on the oxidation of gaseous CH3OH/H2O mixtures in a Proton Exchange Membrane Fuel Cell at T = 100 °C are presented. The catalyst loading of gas diffusion electrodes for anode and cathode was 1 mg/cm2. With a Pt0.7Ru0.3 anode catalyst and Pt as cathode catalyst current densities of > 0.1 A/cm2 at 0.4 V were obtained." @default.
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- W2911902698 date "1995-01-01" @default.
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- W2911902698 title "DEMS and Single Cell Measurements of a Direct Methanol Fuel Cell" @default.
- W2911902698 doi "https://doi.org/10.1149/199523.0267pv" @default.
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