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- W2912013026 endingPage "3271" @default.
- W2912013026 startingPage "3267" @default.
- W2912013026 abstract "Abstract Syntheses of a bulky carbazole‐based substituent, the parent 1,8‐bis(3,5‐di‐ tert ‐butylphenyl)‐3,6‐di‐ tert ‐butyl‐carbazole (R−H) and a series of chlorotetrylenes, RECl (E=Ge, Sn, Pb), are described. Detailed analysis of the properties of the carbazole‐based substituent revealed that it features flexible high bulkiness and electronic non‐innocence, which may make it suitable for many applications in both main‐group and transition‐metal chemistry. To further showcase the employability of the novel substituent, the chlorotetrylenes were subjected to halide abstraction reactions, affording the corresponding tetrylenium salts [RE][Al(OC 4 F 9 ) 4 ] (E=Ge, Sn, Pb) as strongly coloured compounds." @default.
- W2912013026 created "2019-02-21" @default.
- W2912013026 creator A5022813225 @default.
- W2912013026 date "2019-02-04" @default.
- W2912013026 modified "2023-10-01" @default.
- W2912013026 title "Pseudo‐One‐Coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent" @default.
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- W2912013026 doi "https://doi.org/10.1002/chem.201806346" @default.
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