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- W2912021329 abstract "Lactamomethylsilanes of γ-butyrolactam, δ-valerolactam, ε-caprolactam, and 1-isoindolinone (phthalimidine) with up to three methyl moieties were synthesized according to the chemical formula MexSiLac(4–x) (x = 0, 1, 2, and 3). Using the lactams as starting materials four synthetic routes were tested: salt elimination, transsilylation, transamination, and metallation of the lactames followed by reaction with methylchlorosilanes. All products were analyzed by NMR (1H, 13C and 29Si) and RAMAN spectroscopy. Selected solid products were crystallized and the molecular structure was determined by single-crystal X-ray diffraction. The reactivity of the lactamomethylsilanes towards phenylisocyanate and CO2 was studied." @default.
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- W2912021329 date "2019-02-05" @default.
- W2912021329 modified "2023-09-24" @default.
- W2912021329 title "Lactamomethylsilanes - Synthesis, Structures, and Reactivity towards CO<sub>2</sub> and Phenylisocyanate" @default.
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- W2912021329 doi "https://doi.org/10.1002/zaac.201800424" @default.
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