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- W2912030040 abstract "A series of “abnormal” NHC ligand precursors based on imidazopyridines and their corresponding NHC-palladium diiodide complexes were prepared. Our study included the first report on a palladium complex with an abnormal NHC ligand derived from imidazo[1,5-a]pyridine. DFT calculation on the free ligands confirmed the higher electron-donating properties of the abnormal NHC ligands than their normal NHC isomers. The structural properties of all the complexes were studied in detail by single-crystal X-ray diffraction studies, revealing that, in general, Pd–carbene bond distances in palladium complexes with abnormal NHCs were longer than those in their isomers with normal NHCs. A significant trans influence is observed in the palladium complexes with abnormal NHC ligands. But in the complexes with normal NHC ligands, both Pd–carbene and Pd–N bond distances are short. Catalytic studies revealed that the palladium complexes were very efficient in catalyzing direct C–H arylation between 1,2-dimethylimidazole and aryl halides using a low Pd loading of 0.5 mol %. The difference in catalytic activity between the normal and abnormal isomers is, however, small." @default.
- W2912030040 created "2019-02-21" @default.
- W2912030040 creator A5008315490 @default.
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- W2912030040 creator A5075504894 @default.
- W2912030040 creator A5050421567 @default.
- W2912030040 date "2019-02-15" @default.
- W2912030040 modified "2023-10-10" @default.
- W2912030040 title "Isomeric Palladium Complexes Bearing Imidazopyridine-Based Abnormal Carbene Ligands: Synthesis, Characterization, and Catalytic Activity in Direct C–H Arylation Reaction" @default.
- W2912030040 cites W1552068676 @default.
- W2912030040 cites W1865248177 @default.
- W2912030040 cites W1936048884 @default.
- W2912030040 cites W1965539465 @default.
- W2912030040 cites W1974115964 @default.
- W2912030040 cites W1975367720 @default.
- W2912030040 cites W1977184119 @default.
- W2912030040 cites W1996802437 @default.
- W2912030040 cites W1997113667 @default.
- W2912030040 cites W2001663866 @default.
- W2912030040 cites W2002374188 @default.
- W2912030040 cites W2003012557 @default.
- W2912030040 cites W2003554036 @default.
- W2912030040 cites W2003555872 @default.
- W2912030040 cites W2005227604 @default.
- W2912030040 cites W2007514336 @default.
- W2912030040 cites W2011851250 @default.
- W2912030040 cites W2015262040 @default.
- W2912030040 cites W2018537314 @default.
- W2912030040 cites W2019443717 @default.
- W2912030040 cites W2022420285 @default.
- W2912030040 cites W2023271753 @default.
- W2912030040 cites W2023539002 @default.
- W2912030040 cites W2028160394 @default.
- W2912030040 cites W2035536419 @default.
- W2912030040 cites W2035709543 @default.
- W2912030040 cites W2038974680 @default.
- W2912030040 cites W2040488632 @default.
- W2912030040 cites W2046286719 @default.
- W2912030040 cites W2054968002 @default.
- W2912030040 cites W2055935925 @default.
- W2912030040 cites W2056629007 @default.
- W2912030040 cites W2057370118 @default.
- W2912030040 cites W2063090974 @default.
- W2912030040 cites W2067226609 @default.
- W2912030040 cites W2069966030 @default.
- W2912030040 cites W2078039000 @default.
- W2912030040 cites W2083849803 @default.
- W2912030040 cites W2093125996 @default.
- W2912030040 cites W2095187766 @default.
- W2912030040 cites W2099891552 @default.
- W2912030040 cites W2104057453 @default.
- W2912030040 cites W2105007011 @default.
- W2912030040 cites W2109254975 @default.
- W2912030040 cites W2110496741 @default.
- W2912030040 cites W2122031375 @default.
- W2912030040 cites W2131350133 @default.
- W2912030040 cites W2143981217 @default.
- W2912030040 cites W2146928339 @default.
- W2912030040 cites W2147818730 @default.
- W2912030040 cites W2151902009 @default.
- W2912030040 cites W2152083435 @default.
- W2912030040 cites W2152876843 @default.
- W2912030040 cites W2163256558 @default.
- W2912030040 cites W2169269629 @default.
- W2912030040 cites W2235113521 @default.
- W2912030040 cites W2315640677 @default.
- W2912030040 cites W2317299716 @default.
- W2912030040 cites W2318678499 @default.
- W2912030040 cites W2323742323 @default.
- W2912030040 cites W2325709403 @default.
- W2912030040 cites W2325976547 @default.
- W2912030040 cites W2395307562 @default.
- W2912030040 cites W2478943626 @default.
- W2912030040 cites W2518377031 @default.
- W2912030040 cites W2556705129 @default.
- W2912030040 cites W2559401247 @default.
- W2912030040 cites W2580800740 @default.
- W2912030040 cites W2605029271 @default.
- W2912030040 cites W2612555394 @default.
- W2912030040 cites W2746701507 @default.
- W2912030040 cites W2785844295 @default.
- W2912030040 cites W2794655937 @default.
- W2912030040 cites W2883327144 @default.
- W2912030040 cites W2951103459 @default.
- W2912030040 cites W4231660487 @default.
- W2912030040 doi "https://doi.org/10.1021/acs.organomet.8b00806" @default.
- W2912030040 hasPublicationYear "2019" @default.
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