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• W2912040022 startingPage "584" @default.
• W2912040022 abstract "A simple approach to fabricating nanoporous structures and their functionality is demonstrated using a triblock copolymer of polystyrene-b-poly(methyl methacrylate)-b-poly(tert-butyl acrylate) (PS-b-PMMA-b-PtBA), where a continuous-type morphology is set in PS matrix to form the cylinders consisting of the PMMA and minor PtBA blocks. For directional and uniform nanochannels at the interfaces, a perpendicular orientation of cylinders was exploited near two interfaces of air/polymer and polymer/neutral substrate, sandwiching the random orientation of cylinders in the interior of the film. Nondegradative, selective swelling–deswelling process of cylindrical (PMMA-b-PtBA) blocks generates nanopores as an effective route to precisely tune the pore size. Further, a simple hydrolysis of tBA units functionalizes the nanopore surfaces and walls into poly(acrylic acid) layers. We demonstrate the pH-responsive water permeability of nanoporous membranes and their active switching with respect to biomolecules such as bovine serum albumin (BSA), suggesting a feasible functional platform to fabricate a stimuli-responsive ultrafiltration membrane using a tunable multiblock copolymer." @default.
• W2912040022 created "2019-02-21" @default.
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• W2912040022 date "2019-02-15" @default.
• W2912040022 modified "2023-10-11" @default.
• W2912040022 title "Nanoporous Structures from PS-<i>b</i>-PMMA-<i>b</i>-P<i>t</i>BA Triblock Copolymer and Selective Modification for Ultrafiltration Membranes" @default.
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• W2912040022 doi "https://doi.org/10.1021/acsapm.9b00050" @default.
• W2912040022 hasPublicationYear "2019" @default.
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