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- W2912063387 abstract "Region- and diastereoselective reactions involve the corresponding reductions (-coupling) reactions, cycoadditions, and many other reaction types with or without chiral catalysts. Conformational study is introduced using low temperature NMR technology or computational methods using B3LYP/6-311++G(d,p) method with (or without) solvents change using different model (PCM or others), respectively. It is also important in reaction procedure since different molecular orientation may decide different region- or stereoselective products formation. Under the catalysis of chiral catalyst, many new stereogenic centers could be constructed for various compounds. Various substrate are discussed in different reactions. Calculations of transition state energy or others are discussed to explain the corresponding experimental results." @default.
- W2912063387 created "2019-02-21" @default.
- W2912063387 creator A5028387147 @default.
- W2912063387 date "2015-06-26" @default.
- W2912063387 modified "2023-09-28" @default.
- W2912063387 title "Stereoselective Reaction" @default.
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- W2912063387 doi "https://doi.org/10.1002/9783527688166.ch9" @default.
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