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- W2912072146 abstract "The first examples of stable, crystalline, and air-sensitive 1,4-digermabenzenes were isolated. These species photochemically isomerize into the corresponding air-stable digerma-Dewar-benzenes. More importantly, alkyl-substituted Dewar-type-1,4-digermabenzenes can be considered as reversible “air-stable activators” for small molecules such as dihydrogen, carbon dioxide, and acetylene at room temperature. The regeneration of these activators can be accomplished via a thermal retro-isomerization that affords the corresponding 1,4-digermabenzenes." @default.
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- W2912072146 date "2019-02-01" @default.
- W2912072146 modified "2023-10-18" @default.
- W2912072146 title "Reversible Isomerizations between 1,4-Digermabenzenes and 1,4-Digerma-Dewar-benzenes: Air-Stable Activators for Small Molecules" @default.
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- W2912072146 doi "https://doi.org/10.1021/jacs.9b00129" @default.
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