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- W2912086883 abstract "Two current peaks are observed during a negative voltammetric sweep in low to moderate concentrations of H2SO4. The first peak (peak 1) shows negligible effect of substrate. The second peak (peak 2), on the other hand, is markedly influenced by the choice of substrate.The proposed mechanism of peak 2 is based upon the formation of blocking Schottky-type barrier at the substrate-semiconductor interface. This barrier is higher on Au than on Pt due to the different electronegativities of these two metals leading to low and high reverse currents respectively. Glassy carbon, which is a semimetal, forms an heterojunction with MnO2 with a barrier height which is probably similar to that an Au. However due to the reduced carrier concentration in GC compared with a metal the barrier height decreases with increasing cathodic overvoltage resulting in the observed peak 2 behaviour." @default.
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- W2912086883 date "1966-08-01" @default.
- W2912086883 modified "2023-10-14" @default.
- W2912086883 title "Barrier energies in metal-silicon dioxide-silicon structures" @default.
- W2912086883 doi "https://doi.org/10.1016/0038-1098(66)90261-4" @default.
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