FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912094215> ?p ?o ?g. }

• W2912094215 endingPage "149" @default.
• W2912094215 startingPage "145" @default.
• W2912094215 abstract "With an aim to obtain a new supramolecular compound based on Keggin-type polyoxometalates with mixed-ligand: [Cu(I)(phen)2]2{[Cu(II)]2(phen)4PTA}[H3PMoV4MoVI8O40] (phen = 1,10-phenanthroline, PTA = terephthalic acid) has been synthesized under hydrothermal conditions and structurally characterized by elemental analyses, IR, X-ray single crystal diffraction, TG analyses and XPS. In the title compound, the Keggin-type phosphomolybates anions, butterfly-shaped [Cu(I)(phen)2]+ subunits and dumbbell-shaped {[Cu(II)]2(phen)4PTA}2+ subunits are alternately connected to form chiral helical chains via hydrogen bonds along b axis, and the adjacent chiral helical chains are connected in the way of sharing butterfly-shaped [Cu(I)(phen)2]+ subunits and dumbbell-shaped {[Cu(II)]2(phen)4PTA}2+ subunits to form 3D supramolecular reticular framework. As expected, the title compound with mixed-ligands (phen and PTA) has been successfully synthesized, inconceivably, the title compound also contains mixed-valence Cu (Cu(I) in butterfly-shaped [Cu(I)(phen)2]+ subunits; Cu(II) in dumbbell-shaped {[Cu(II)]2(phen)4PTA}2+ subunits). The preliminary analyses show that mixed-valence Cu(I/II) may be due to the reduction of Cu(II) (from CuCl2) to Cu(I) (in butterfly-shaped [Cu(I)(phen)2]+ subunits) by N-containing compound. The successful results of this work provide a new idea that supramolecular materials with attractive structures and novel properties, which could be designed and synthesized by introducing of mixed-ligands into the supramolecular materials. Additionally, the electrocatalytic property of the title compound to H2O2 has been studied." @default.
• W2912094215 created "2019-02-21" @default.
• W2912094215 creator A5015299890 @default.
• W2912094215 creator A5018729969 @default.
• W2912094215 creator A5027390010 @default.
• W2912094215 creator A5035456557 @default.
• W2912094215 creator A5051229707 @default.
• W2912094215 creator A5054037353 @default.
• W2912094215 creator A5062673325 @default.
• W2912094215 creator A5069255958 @default.
• W2912094215 creator A5080037549 @default.
• W2912094215 date "2019-03-01" @default.
• W2912094215 modified "2023-10-14" @default.
• W2912094215 title "A new supramolecular compound based on Keggin-type phosphomolybates with mixed-ligand and mixed-valence Cu(I/II): [Cu(I)(phen)2]2{[Cu(II)]2(phen)4PTA}[H3PMo8VIMo4VO40]" @default.
• W2912094215 cites W1969142803 @default.
• W2912094215 cites W2015122610 @default.
• W2912094215 cites W2017908445 @default.
• W2912094215 cites W2026182953 @default.
• W2912094215 cites W2029649448 @default.
• W2912094215 cites W2030756845 @default.
• W2912094215 cites W2035127456 @default.
• W2912094215 cites W2083407417 @default.
• W2912094215 cites W2104608846 @default.
• W2912094215 cites W2152902542 @default.
• W2912094215 cites W2166226739 @default.
• W2912094215 cites W2195312443 @default.
• W2912094215 cites W2310788654 @default.
• W2912094215 cites W2320165097 @default.
• W2912094215 cites W2510061864 @default.
• W2912094215 cites W2530651762 @default.
• W2912094215 cites W2551890066 @default.
• W2912094215 cites W2617435693 @default.
• W2912094215 cites W2763910699 @default.
• W2912094215 cites W2783921982 @default.
• W2912094215 cites W2951758507 @default.
• W2912094215 cites W2952262952 @default.
• W2912094215 cites W4231341983 @default.
• W2912094215 cites W4253733131 @default.
• W2912094215 cites W571677485 @default.
• W2912094215 doi "https://doi.org/10.1016/j.inoche.2019.01.037" @default.
• W2912094215 hasPublicationYear "2019" @default.
• W2912094215 type Work @default.
• W2912094215 sameAs 2912094215 @default.
• W2912094215 citedByCount "5" @default.
• W2912094215 countsByYear W29120942152021 @default.
• W2912094215 countsByYear W29120942152022 @default.
• W2912094215 crossrefType "journal-article" @default.
• W2912094215 hasAuthorship W2912094215A5015299890 @default.
• W2912094215 hasAuthorship W2912094215A5018729969 @default.
• W2912094215 hasAuthorship W2912094215A5027390010 @default.
• W2912094215 hasAuthorship W2912094215A5035456557 @default.
• W2912094215 hasAuthorship W2912094215A5051229707 @default.
• W2912094215 hasAuthorship W2912094215A5054037353 @default.
• W2912094215 hasAuthorship W2912094215A5062673325 @default.
• W2912094215 hasAuthorship W2912094215A5069255958 @default.
• W2912094215 hasAuthorship W2912094215A5080037549 @default.
• W2912094215 hasConcept C115624301 @default.
• W2912094215 hasConcept C116569031 @default.
• W2912094215 hasConcept C168900304 @default.
• W2912094215 hasConcept C170493617 @default.
• W2912094215 hasConcept C178790620 @default.
• W2912094215 hasConcept C185592680 @default.
• W2912094215 hasConcept C1862650 @default.
• W2912094215 hasConcept C2776546559 @default.
• W2912094215 hasConcept C544778455 @default.
• W2912094215 hasConcept C55493867 @default.
• W2912094215 hasConcept C71240020 @default.
• W2912094215 hasConcept C71924100 @default.
• W2912094215 hasConcept C73922627 @default.
• W2912094215 hasConcept C8010536 @default.
• W2912094215 hasConcept C93275456 @default.
• W2912094215 hasConceptScore W2912094215C115624301 @default.
• W2912094215 hasConceptScore W2912094215C116569031 @default.
• W2912094215 hasConceptScore W2912094215C168900304 @default.
• W2912094215 hasConceptScore W2912094215C170493617 @default.
• W2912094215 hasConceptScore W2912094215C178790620 @default.
• W2912094215 hasConceptScore W2912094215C185592680 @default.
• W2912094215 hasConceptScore W2912094215C1862650 @default.
• W2912094215 hasConceptScore W2912094215C2776546559 @default.
• W2912094215 hasConceptScore W2912094215C544778455 @default.
• W2912094215 hasConceptScore W2912094215C55493867 @default.
• W2912094215 hasConceptScore W2912094215C71240020 @default.
• W2912094215 hasConceptScore W2912094215C71924100 @default.
• W2912094215 hasConceptScore W2912094215C73922627 @default.
• W2912094215 hasConceptScore W2912094215C8010536 @default.
• W2912094215 hasConceptScore W2912094215C93275456 @default.
• W2912094215 hasFunder F4320321001 @default.
• W2912094215 hasLocation W29120942151 @default.
• W2912094215 hasOpenAccess W2912094215 @default.
• W2912094215 hasPrimaryLocation W29120942151 @default.
• W2912094215 hasRelatedWork W1999828662 @default.
• W2912094215 hasRelatedWork W2012675768 @default.
• W2912094215 hasRelatedWork W2056714810 @default.
• W2912094215 hasRelatedWork W2068195042 @default.
• W2912094215 hasRelatedWork W2093132841 @default.
• W2912094215 hasRelatedWork W2150940904 @default.
• W2912094215 hasRelatedWork W2152994084 @default.
• W2912094215 hasRelatedWork W2362282816 @default.

• next