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- W2912094871 abstract "Abstract Temperature programmed desorption - mass spectrometry was utilized to study the non-isothermal hydrogen desorption from as-received and pre-oxidized TiH2 powder samples. Above the temperature of 750 °C, hydrogen desorption from the thermally decomposed as-received powder is kinetically delayed compared to that from the pre-oxidized samples. The scanning electron microscopy observations suggest that the delay stems from simultaneous surface coarsening and particles sintering that occur predominantly in the as-received powder at lower temperatures. It is also suggested that the difference in morphology evolution of the as-received and pre-oxidized powders originates from the dependence of Ti diffusion on the concentration of oxygen dissolved in Ti, since the oxide layer itself was found to dissociate at lower temperatures (∼500 °C)." @default.
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- W2912094871 date "2019-03-01" @default.
- W2912094871 modified "2023-09-27" @default.
- W2912094871 title "The role of surface coarsening and sintering during thermal decomposition of titanium hydride" @default.
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- W2912094871 doi "https://doi.org/10.1016/j.ijhydene.2019.01.070" @default.
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