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- W2912109656 startingPage "1114" @default.
- W2912109656 abstract "Molecular and crystal structure of a 1 : 1 molecular complex of tetraethylene glycol dimethyl ether CH3O-(CH2CH2O)4CH3 (TGM) with mercuric chloride has been determined by means of X-ray diffraction. The complex has a monoclinic unit cell with a=14.29, b=15.10, c=7.84 A, and β=97.0°. The space group is P21/n. Four molecules of both TGM and mercuric chloride are contained in the unit cell. The structure was determined by the ordinary heavy atom method. The molecular conformation of TGM in the complex is approximately CH3–OundersetT–CH2undersetG–CH2undersetT–OundersetT–CH2undersetbarG–CH2undersetT–OundersetT–CH2undersetG–CH2undersetT–OundersetT–CH2undersetbarG–CH2undersetT–OundersetT–CH2undersetG–CH2undersetT–O–CH3, where T, G, and barG indicate trans, gauche, and minus gauche forms, respectively. All the CH2–O bonds are trans, while the CH2–CH2 bonds are gauche and minus gauche in the adjacent chemical units. The conforma-tional unit of OundersetT–CH2undersetG–CH2undersetT–OundersetT–C..." @default.
- W2912109656 created "2019-02-21" @default.
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- W2912109656 date "1973-04-01" @default.
- W2912109656 modified "2023-10-10" @default.
- W2912109656 title "Structure of Ethylene Oxide Oligomer Complexes. I. A 1:1 Complex of Tetraethylene Glycol Dimethyl Ether with Mercuric Chloride" @default.
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- W2912109656 doi "https://doi.org/10.1246/bcsj.46.1114" @default.
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