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• W2912115890 endingPage "3031" @default.
• W2912115890 startingPage "2954" @default.
• W2912115890 abstract "Copper is one of the most abundant and less toxic transition metals. Nature takes advantage of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase organic transformations using O2 (or H2O2) as oxidant. Inspired by the reactivity of these Cu-dependent metalloenzymes, chemists have developed synthetic protocols to functionalize organic molecules under enviormentally benign conditions. Copper also promotes other transformations usually catalyzed by 4d and 5d transition metals (Pd, Pt, Rh, etc.) such as nitrene insertions or C-C and C-heteroatom coupling reactions. In this review, we summarized the most relevant research in which copper promotes or catalyzes the functionalization of organic molecules, including biological catalysis, bioinspired model systems, and organometallic reactivity. The reaction mechanisms by which these processes take place are discussed in detail." @default.
• W2912115890 created "2019-02-21" @default.
• W2912115890 creator A5054821271 @default.
• W2912115890 creator A5071146834 @default.
• W2912115890 creator A5090859264 @default.
• W2912115890 date "2019-01-30" @default.
• W2912115890 modified "2023-10-18" @default.
• W2912115890 title "Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂Model Systems to Organometallic Transformations" @default.
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