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- W2912116719 abstract "A modulated coherent (La,Sr)CoO3-δ/(Ce,Gd)O2-δ heterostructure is characterized for the first time for its electronic and chemical properties. 2D-multilayer architectures are deposited on NdGaO3 (110) single crystal substrate by pulsed laser deposition, resulting in epitaxial structures with in-plane lattice rotation that, via the metal oxides' interfaces, induces mutual structural rearrangements. Our results show that (La,Sr)CoO3-d thin films of 10-100 nm are chemically unstable when exposed to air at 600 °C during electrical cyclic stress-tests. Conversely, improved stability is achieved confining LSC in the nanometric heterostructure. Remarkably, the chemical stabilization occurs without compromising substantially the electrical properties of the LSC component: the heterostructures show unexpected electrical behaviour with dominant electronic contributions, fast conductivity and mixed ionic-electronic properties, depending on the number of interfaces and the nano-scaled layers." @default.
- W2912116719 created "2019-02-21" @default.
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- W2912116719 date "2019-01-01" @default.
- W2912116719 modified "2023-10-17" @default.
- W2912116719 title "Electrochemical stability of (La,Sr)CoO<sub>3−δ</sub> in (La,Sr)CoO<sub>3−δ</sub>/(Ce, Gd)O<sub>2−δ</sub> heterostructures" @default.
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- W2912116719 doi "https://doi.org/10.1039/c8nr08528e" @default.
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