Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912122368> ?p ?o ?g. }
- W2912122368 endingPage "6563" @default.
- W2912122368 startingPage "6559" @default.
- W2912122368 abstract "Abstract Engineering low‐band‐gap π‐conjugated polymers is a growing area in basic and applied research. The main synthetic challenge lies in the solubility of the starting materials, which precludes advancements in the field. Here, we report an on‐surface synthesis protocol to overcome such difficulties and produce poly( p ‐anthracene ethynylene) molecular wires on Au(111). To this aim, a quinoid anthracene precursor with =CBr 2 moieties is deposited and annealed to 400 K, resulting in anthracene‐based polymers. High‐resolution nc‐AFM measurements confirm the nature of the ethynylene‐bridge bond between the anthracene moieties. Theoretical simulations illustrate the mechanism of the chemical reaction, highlighting three major steps: dehalogenation, diffusion of surface‐stabilized carbenes, and homocoupling, which enables the formation of an ethynylene bridge. Our results introduce a novel chemical protocol to design π‐conjugated polymers based on oligoacene precursors and pave new avenues for advancing the emerging field of on‐surface synthesis." @default.
- W2912122368 created "2019-02-21" @default.
- W2912122368 creator A5001945321 @default.
- W2912122368 creator A5006279877 @default.
- W2912122368 creator A5008464293 @default.
- W2912122368 creator A5011454444 @default.
- W2912122368 creator A5024477186 @default.
- W2912122368 creator A5038969515 @default.
- W2912122368 creator A5041956422 @default.
- W2912122368 creator A5061345517 @default.
- W2912122368 creator A5065851393 @default.
- W2912122368 creator A5068199059 @default.
- W2912122368 creator A5077791406 @default.
- W2912122368 creator A5081534068 @default.
- W2912122368 creator A5082274397 @default.
- W2912122368 creator A5085477254 @default.
- W2912122368 creator A5086268718 @default.
- W2912122368 date "2019-03-12" @default.
- W2912122368 modified "2023-10-07" @default.
- W2912122368 title "On‐Surface Synthesis of Ethynylene‐Bridged Anthracene Polymers" @default.
- W2912122368 cites W1412386274 @default.
- W2912122368 cites W1986670239 @default.
- W2912122368 cites W2028253542 @default.
- W2912122368 cites W2058595066 @default.
- W2912122368 cites W2067778667 @default.
- W2912122368 cites W2089430481 @default.
- W2912122368 cites W2101850500 @default.
- W2912122368 cites W2140372631 @default.
- W2912122368 cites W2258047439 @default.
- W2912122368 cites W2263605768 @default.
- W2912122368 cites W2293126824 @default.
- W2912122368 cites W2293827968 @default.
- W2912122368 cites W2314095240 @default.
- W2912122368 cites W2328382804 @default.
- W2912122368 cites W2564322061 @default.
- W2912122368 cites W2596085367 @default.
- W2912122368 cites W2742685874 @default.
- W2912122368 cites W2743493043 @default.
- W2912122368 cites W2745305113 @default.
- W2912122368 cites W2746050985 @default.
- W2912122368 cites W2748116613 @default.
- W2912122368 cites W2766535472 @default.
- W2912122368 cites W2789801316 @default.
- W2912122368 cites W2790221239 @default.
- W2912122368 cites W2790755186 @default.
- W2912122368 cites W2791385437 @default.
- W2912122368 cites W2803943387 @default.
- W2912122368 cites W2883718919 @default.
- W2912122368 cites W2887230501 @default.
- W2912122368 cites W2895149573 @default.
- W2912122368 cites W3103825220 @default.
- W2912122368 cites W4234202583 @default.
- W2912122368 cites W4240865467 @default.
- W2912122368 cites W4241169658 @default.
- W2912122368 cites W4250130250 @default.
- W2912122368 cites W4293119789 @default.
- W2912122368 doi "https://doi.org/10.1002/anie.201814154" @default.
- W2912122368 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6563096" @default.
- W2912122368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30761719" @default.
- W2912122368 hasPublicationYear "2019" @default.
- W2912122368 type Work @default.
- W2912122368 sameAs 2912122368 @default.
- W2912122368 citedByCount "43" @default.
- W2912122368 countsByYear W29121223682019 @default.
- W2912122368 countsByYear W29121223682020 @default.
- W2912122368 countsByYear W29121223682021 @default.
- W2912122368 countsByYear W29121223682022 @default.
- W2912122368 countsByYear W29121223682023 @default.
- W2912122368 crossrefType "journal-article" @default.
- W2912122368 hasAuthorship W2912122368A5001945321 @default.
- W2912122368 hasAuthorship W2912122368A5006279877 @default.
- W2912122368 hasAuthorship W2912122368A5008464293 @default.
- W2912122368 hasAuthorship W2912122368A5011454444 @default.
- W2912122368 hasAuthorship W2912122368A5024477186 @default.
- W2912122368 hasAuthorship W2912122368A5038969515 @default.
- W2912122368 hasAuthorship W2912122368A5041956422 @default.
- W2912122368 hasAuthorship W2912122368A5061345517 @default.
- W2912122368 hasAuthorship W2912122368A5065851393 @default.
- W2912122368 hasAuthorship W2912122368A5068199059 @default.
- W2912122368 hasAuthorship W2912122368A5077791406 @default.
- W2912122368 hasAuthorship W2912122368A5081534068 @default.
- W2912122368 hasAuthorship W2912122368A5082274397 @default.
- W2912122368 hasAuthorship W2912122368A5085477254 @default.
- W2912122368 hasAuthorship W2912122368A5086268718 @default.
- W2912122368 hasBestOaLocation W29121223681 @default.
- W2912122368 hasConcept C112613896 @default.
- W2912122368 hasConcept C115537861 @default.
- W2912122368 hasConcept C147789679 @default.
- W2912122368 hasConcept C155574463 @default.
- W2912122368 hasConcept C171250308 @default.
- W2912122368 hasConcept C178790620 @default.
- W2912122368 hasConcept C185592680 @default.
- W2912122368 hasConcept C188027245 @default.
- W2912122368 hasConcept C192562407 @default.
- W2912122368 hasConcept C21951064 @default.
- W2912122368 hasConcept C2779563022 @default.
- W2912122368 hasConcept C521977710 @default.
- W2912122368 hasConcept C65973085 @default.