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- W2912136575 abstract "Efficient conditions have been developed for the diastereoselective aziridination of the biomass pyrolysis product (−)-levoglucosenone, via the reaction of primary aliphatic amines with 3-iodolevoglucosenone. In contrast to the reactions of aliphatic amines, the use of 4-methoxyaniline resulted in an aza-Michael-initiated dimerisation reaction, and 1,3-diphenylurea gave a 2-imidazolidinone. The aziridine products were transformed using the aza-Wharton reaction, affording novel sulfonamide and amine-substituted 6,8-dioxabicyclo[3.2.1]oct-3-enes with potential as sp3-rich chiral scaffolds." @default.
- W2912136575 created "2019-02-21" @default.
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- W2912136575 date "2019-01-01" @default.
- W2912136575 modified "2023-09-26" @default.
- W2912136575 title "Aziridination and aza-Wharton Reactions of Levoglucosenone" @default.
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- W2912136575 doi "https://doi.org/10.1071/ch18574" @default.
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