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- W2912155505 abstract "A controllable palladium-catalyzed intramolecular C–H activation of N-alkyl-N-arylanthranilic acids has been developed. The methodology allows selective synthesis of 1,2-dihydro-(4H)-3,1-benzoxazin-4-ones and carbazoles from the same starting materials and palladium catalyst. The selectivity is controlled by the oxidant. Silver oxide promotes C(sp3)–H activation/C–O cyclization to provide 1,2-dihydro-(4H)-3,1-benzoxazin-4-ones, while copper acetate contributes to C(sp2)–H activation/decarboxylative arylation to afford carbazoles. This protocol is demonstrated by its wide substrate scope and good functional group tolerance." @default.
- W2912155505 created "2019-02-21" @default.
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- W2912155505 date "2019-01-29" @default.
- W2912155505 modified "2023-10-14" @default.
- W2912155505 title "Pd-Catalyzed Intramolecular Chemoselective C(sp2)–H and C(sp3)–H Activation of <i>N</i>-Alkyl-<i>N</i>-arylanthranilic Acids" @default.
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- W2912155505 doi "https://doi.org/10.1021/acs.orglett.8b03976" @default.
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