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- W2912161229 abstract "The operationally simple palladium-catalyzed double-bond migration without heteroatom-containing coordinating functional groups is described. Addition of TaCl5 as a second catalyst greatly enhanced the migration efficiency to provide β-alkylstyrenes through migration of up to a five-carbon chain. Both catalysts were commercially available, and the reaction occurred without external ligands under neutral conditions. The reaction proceeded via generation of π-allyl palladium species, which enabled the chemoselective double-bond migration of hydrocarbons in the presence of allylethers. Remote functionalization through double-bond migration was also demonstrated using FeCl3 as a second catalyst." @default.
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- W2912161229 date "2019-01-01" @default.
- W2912161229 modified "2023-09-26" @default.
- W2912161229 title "Palladium-catalyzed double-bond migration of unsaturated hydrocarbons accelerated by tantalum chloride" @default.
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- W2912161229 doi "https://doi.org/10.1039/c9cc00223e" @default.
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