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- W2912162675 abstract "Abstract The elucidation of the reaction rate-determining step nature in intercalation processes is essential for the development of approaches for the precise control of rate-limiting factors. In this work, we explore the kinetic patterns of lithium-ion intercalation into two model cathode materials (LiCoO2 and LiMn2O4) and develop criteria for distinguishing between Butler-Volmer slow charge transfer and slow chemical steps. A numerical model for the rate-limiting ion desolvation step is developed and the predictions of the model are compared with the experimental voltammetric and electrochemical impedance spectroscopy data. We show that slow desolvation step results in essential changes in the shape of both cyclic voltammetry and impedance responses with the kinetic resistance vs. potential dependencies being highly informative for the reaction rate control diagnostics. The consideration of the intercalation kinetics in four solvents (water, propylene carbonate, acetonitrile and dimethyl sulfoxide) allows concluding on the influence of the resistivity of surface layer/electrode material interface on the reaction slow step nature." @default.
- W2912162675 created "2019-02-21" @default.
- W2912162675 creator A5003737880 @default.
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- W2912162675 date "2019-04-01" @default.
- W2912162675 modified "2023-09-29" @default.
- W2912162675 title "Diagnostics of lithium-ion intercalation rate-determining step: Distinguishing between slow desolvation and slow charge transfer" @default.
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- W2912162675 doi "https://doi.org/10.1016/j.electacta.2019.02.043" @default.
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