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- W2912164564 endingPage "1262" @default.
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- W2912164564 abstract "A pioneering chemiluminescent molecule reported by Schaap and co-workers, 3-(2′-spiroadamantane)-4-methoxy-4-(3″-hydroxy)phenyl-1,2-dioxetane (AMPD), does not require enzymatic activation but is unsuitable for use under physiological conditions. To overcome this limitation, we have developed a new AMPD derivative that contains an acetamido group at the ortho position of the hydroxy group as an intramolecular hydrogen-bonding site in order to lower the pKa value. This compound exhibits a superior chemiluminescence response to AMPD in the physiologically relevant pH range." @default.
- W2912164564 created "2019-02-21" @default.
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- W2912164564 date "2019-02-15" @default.
- W2912164564 modified "2023-10-17" @default.
- W2912164564 title "Effect of the <i>o</i>-Acetamido Group on pH-Dependent Light Emission of a 3-Hydroxyphenyl-Substituted Dioxetane Luminophore" @default.
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- W2912164564 doi "https://doi.org/10.1021/acs.orglett.8b03913" @default.
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- W2912164564 hasPublicationYear "2019" @default.
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