Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912182464> ?p ?o ?g. }
- W2912182464 endingPage "4926" @default.
- W2912182464 startingPage "4920" @default.
- W2912182464 abstract "Controllable synthesis of highly-branched metallic structures is of great interest and broad significance for their unique properties of superior conductivity, high porosity, low density, etc., that promote the development of high-efficiency electrocatalysts. Herein, a simple, rapid and green method for the synthesis of highly-branched palladium nanodandelions with flexible ultrafine tentacles and bumpy superficial atomic steps is investigated, without the demand of elevated temperature, seed, template, prolonged reaction time and any organically toxic reducing agent from previously reported highly-branched nanostructures. For the first time, N,N'-methylenebisacrylamide (MBAA) serves as the only additive to simultaneously cover the functions of coordinating agent, reducing agent, and structure-directing agent, facilitating the strategy of intramolecular coordination and self-reduction. Derived from their plentiful ultrafine tentacles, porosity due to the highly-branched structure, and abundant surface atom steps, the Pd nanodandelions exhibit a more positive half-wave of 0.863 V (vs. RHE), optimized specific kinetic activity of 3.0 mA cm-2 at 0.9 V, and better cycle stability with a maintenance of 77.8 % after 20000 s for the oxygen reduction reaction (ORR), when compared to commercial Pd black. The architectural design of highly-branched metallic structures, as well as the smart fabrication strategy, may hold great promise for exploring a variety of functional nanomaterials." @default.
- W2912182464 created "2019-02-21" @default.
- W2912182464 creator A5004408436 @default.
- W2912182464 creator A5023457334 @default.
- W2912182464 creator A5024295563 @default.
- W2912182464 creator A5051036720 @default.
- W2912182464 creator A5063426256 @default.
- W2912182464 creator A5069945252 @default.
- W2912182464 creator A5071270472 @default.
- W2912182464 creator A5080093115 @default.
- W2912182464 date "2019-03-12" @default.
- W2912182464 modified "2023-10-17" @default.
- W2912182464 title "Highly‐Branched Palladium Nanodandelions: Simple, Fast, and Green Fabrication with Superior Oxygen Reduction Property" @default.
- W2912182464 cites W1701222527 @default.
- W2912182464 cites W1817628599 @default.
- W2912182464 cites W1965362556 @default.
- W2912182464 cites W1983659980 @default.
- W2912182464 cites W1990662490 @default.
- W2912182464 cites W1991547085 @default.
- W2912182464 cites W2004963345 @default.
- W2912182464 cites W2023481289 @default.
- W2912182464 cites W2024628052 @default.
- W2912182464 cites W2025970332 @default.
- W2912182464 cites W2056865418 @default.
- W2912182464 cites W2062311106 @default.
- W2912182464 cites W2080599350 @default.
- W2912182464 cites W2108096535 @default.
- W2912182464 cites W2121230626 @default.
- W2912182464 cites W2121801014 @default.
- W2912182464 cites W2134194378 @default.
- W2912182464 cites W2149668170 @default.
- W2912182464 cites W2172428124 @default.
- W2912182464 cites W2223927465 @default.
- W2912182464 cites W2243888953 @default.
- W2912182464 cites W2282829153 @default.
- W2912182464 cites W2317414015 @default.
- W2912182464 cites W2322513125 @default.
- W2912182464 cites W2340466854 @default.
- W2912182464 cites W2407309672 @default.
- W2912182464 cites W2416575054 @default.
- W2912182464 cites W2417870117 @default.
- W2912182464 cites W2507303425 @default.
- W2912182464 cites W2522850096 @default.
- W2912182464 cites W2554441217 @default.
- W2912182464 cites W2563813999 @default.
- W2912182464 cites W2571699090 @default.
- W2912182464 cites W2606397829 @default.
- W2912182464 cites W2607046457 @default.
- W2912182464 cites W2607089188 @default.
- W2912182464 cites W2732308955 @default.
- W2912182464 cites W2743908024 @default.
- W2912182464 cites W2749741392 @default.
- W2912182464 cites W2754193011 @default.
- W2912182464 cites W2768893838 @default.
- W2912182464 cites W2773504246 @default.
- W2912182464 cites W2774395650 @default.
- W2912182464 cites W2783733080 @default.
- W2912182464 cites W2785656735 @default.
- W2912182464 cites W2793001358 @default.
- W2912182464 cites W2796648595 @default.
- W2912182464 cites W2806188807 @default.
- W2912182464 cites W2808057641 @default.
- W2912182464 cites W4210398367 @default.
- W2912182464 cites W4230993452 @default.
- W2912182464 cites W4256524006 @default.
- W2912182464 doi "https://doi.org/10.1002/chem.201805521" @default.
- W2912182464 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30720901" @default.
- W2912182464 hasPublicationYear "2019" @default.
- W2912182464 type Work @default.
- W2912182464 sameAs 2912182464 @default.
- W2912182464 citedByCount "8" @default.
- W2912182464 countsByYear W29121824642019 @default.
- W2912182464 countsByYear W29121824642020 @default.
- W2912182464 countsByYear W29121824642021 @default.
- W2912182464 countsByYear W29121824642022 @default.
- W2912182464 crossrefType "journal-article" @default.
- W2912182464 hasAuthorship W2912182464A5004408436 @default.
- W2912182464 hasAuthorship W2912182464A5023457334 @default.
- W2912182464 hasAuthorship W2912182464A5024295563 @default.
- W2912182464 hasAuthorship W2912182464A5051036720 @default.
- W2912182464 hasAuthorship W2912182464A5063426256 @default.
- W2912182464 hasAuthorship W2912182464A5069945252 @default.
- W2912182464 hasAuthorship W2912182464A5071270472 @default.
- W2912182464 hasAuthorship W2912182464A5080093115 @default.
- W2912182464 hasConcept C127413603 @default.
- W2912182464 hasConcept C136525101 @default.
- W2912182464 hasConcept C138631740 @default.
- W2912182464 hasConcept C142724271 @default.
- W2912182464 hasConcept C159985019 @default.
- W2912182464 hasConcept C161790260 @default.
- W2912182464 hasConcept C171250308 @default.
- W2912182464 hasConcept C178790620 @default.
- W2912182464 hasConcept C185592680 @default.
- W2912182464 hasConcept C186423591 @default.
- W2912182464 hasConcept C191897082 @default.
- W2912182464 hasConcept C192562407 @default.
- W2912182464 hasConcept C204787440 @default.
- W2912182464 hasConcept C21951064 @default.