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- W2912194438 abstract "The theory of the vibrational angular momentum term(hat pi _alpha ^2 ) in the effective molecular rotational Hamilton operator is briefly reviewed. Novel vibrational matrix elements of(hat pi _alpha ^2 ), off-diagonal in the basis of the coupled linear oscillator basis functions, are derived for asymmetric top molecules. These matrix elements contain two or three distinct vibrational quantum numbers, respectively. A group-theoretical scheme; the use of repeated Jahn’s rules, is given for testing the existence of the proposed matrix elements. Finally suggestions are made for the application of the latter." @default.
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- W2912194438 date "1984-03-01" @default.
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- W2912194438 title "Vibrational angular momentum in the theory of vibration-rotation spectra" @default.
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- W2912194438 doi "https://doi.org/10.1007/bf03155923" @default.
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