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• W2912204227 startingPage "5639" @default.
• W2912204227 abstract "Herein we report the discovery of the intrinsic mechanochemical reactivity of vinyl-addition polynorbornene (VA-PNB), which has strained bicyclic ring repeat units along the polymer backbone. VA-PNBs with three different side chains were found to undergo ring-opening olefination upon sonication in dilute solutions. The sonicated polymers exhibited spectroscopic signatures consistent with conversion of the bicyclic norbornane repeat units into the ring-open isomer typical of polynorbornene made by ring-opening metathesis polymerization (ROMP-PNB). Thermal analysis and evaluation of chain-scission kinetics suggest that sonication of VA-PNB results in chain segments containing a statistical mixture of vinyl-added and ROMP-type repeat units." @default.
• W2912204227 created "2019-02-21" @default.
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• W2912204227 date "2019-03-26" @default.
• W2912204227 modified "2023-09-26" @default.
• W2912204227 title "The Intrinsic Mechanochemical Reactivity of Vinyl‐Addition Polynorbornene" @default.
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• W2912204227 doi "https://doi.org/10.1002/anie.201900467" @default.
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