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- W2912222140 endingPage "9354" @default.
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- W2912222140 abstract "Covalent organic frameworks (COFs) are a family of crystalline porous networks having applications in various fields, including gas and energy storage. Despite respectable progress in the synthesis of such crystalline materials, examples of the use of template-free methods to construct COFs having hollow nano- and microstructures are rare. Furthermore, all reported methods for synthesizing these hollow structural COFs have involved [4 + 2] and [3 + 2] condensations. Herein, we report the synthesis of hollow microspherical and microtubular carbazole-based COFs through template-free, one-pot, [3 + 3] condensations of the novel triamine 9-(4-aminophenyl)-carbazole-3,6-diamine (Car-3NH2) and triformyl linkers with various degrees of planarity. Depending upon the monomer's planarity, a unique morphological variety was observed. A time-dependent study revealed that each COF formed through an individual mechanism depended on the degree of planarity of the triformyl linker; it also confirmed that the hollow structures of these COFs formed through inside-out Ostwald ripening. Our COFs exhibited high Brunauer-Emmett-Teller surface areas (up to ca. 1400 m2 g-1), excellent crystallinity, and high thermal stability. Moreover, the CO2 uptake capacities of these COFs were excellent: up to 61 and 123 mg g-1 at 298 and 273 K, respectively. The high surface areas facilitated greater numbers of strong interactions with CO2 molecules, leading to high CO2 uptake capacities. Moreover, the prepared COFs exhibited redox activity because of their redox-active triphenylamine and pyridine groups, which can be utilized in electrochemical energy storages. Accordingly, such hollow COFs having high surface areas appear to be useful materials for industrial and biological applications." @default.
- W2912222140 created "2019-02-21" @default.
- W2912222140 creator A5037509120 @default.
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- W2912222140 date "2019-02-08" @default.
- W2912222140 modified "2023-10-16" @default.
- W2912222140 title "Hollow Microspherical and Microtubular [3 + 3] Carbazole-Based Covalent Organic Frameworks and Their Gas and Energy Storage Applications" @default.
- W2912222140 cites W1749207617 @default.
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- W2912222140 cites W1968019977 @default.
- W2912222140 cites W1974801467 @default.
- W2912222140 cites W1978696932 @default.
- W2912222140 cites W1979909959 @default.
- W2912222140 cites W1985087175 @default.
- W2912222140 cites W1986888620 @default.
- W2912222140 cites W1987581091 @default.
- W2912222140 cites W1989896216 @default.
- W2912222140 cites W1992843203 @default.
- W2912222140 cites W1994692711 @default.
- W2912222140 cites W2004983112 @default.
- W2912222140 cites W2013200143 @default.
- W2912222140 cites W2013287426 @default.
- W2912222140 cites W2037739444 @default.
- W2912222140 cites W2039462622 @default.
- W2912222140 cites W2048435598 @default.
- W2912222140 cites W2049145344 @default.
- W2912222140 cites W2049541689 @default.
- W2912222140 cites W2050571756 @default.
- W2912222140 cites W2052886839 @default.
- W2912222140 cites W2062122540 @default.
- W2912222140 cites W2073402336 @default.
- W2912222140 cites W2074328510 @default.
- W2912222140 cites W2082139032 @default.
- W2912222140 cites W2086940279 @default.
- W2912222140 cites W2087813165 @default.
- W2912222140 cites W2095608520 @default.
- W2912222140 cites W2104015519 @default.
- W2912222140 cites W2120413458 @default.
- W2912222140 cites W2123289548 @default.
- W2912222140 cites W2128235529 @default.
- W2912222140 cites W2139920822 @default.
- W2912222140 cites W2143730683 @default.
- W2912222140 cites W2149962227 @default.
- W2912222140 cites W2152754138 @default.
- W2912222140 cites W2266733933 @default.
- W2912222140 cites W2275048878 @default.
- W2912222140 cites W2293985824 @default.
- W2912222140 cites W2313218751 @default.
- W2912222140 cites W2314759481 @default.
- W2912222140 cites W2317898558 @default.
- W2912222140 cites W2319195884 @default.
- W2912222140 cites W2322331492 @default.
- W2912222140 cites W2323852127 @default.
- W2912222140 cites W2327311573 @default.
- W2912222140 cites W2329311393 @default.
- W2912222140 cites W2330652626 @default.
- W2912222140 cites W2331449805 @default.
- W2912222140 cites W2405556515 @default.
- W2912222140 cites W2409778596 @default.
- W2912222140 cites W2466085640 @default.
- W2912222140 cites W2522943234 @default.
- W2912222140 cites W2533890368 @default.
- W2912222140 cites W2552458388 @default.
- W2912222140 cites W2568850435 @default.
- W2912222140 cites W2576815768 @default.
- W2912222140 cites W2580073788 @default.
- W2912222140 cites W2586821633 @default.
- W2912222140 cites W2600552459 @default.
- W2912222140 cites W2609764336 @default.
- W2912222140 cites W2766160225 @default.
- W2912222140 cites W2787269252 @default.
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- W2912222140 doi "https://doi.org/10.1021/acsami.8b21867" @default.
- W2912222140 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30735343" @default.
- W2912222140 hasPublicationYear "2019" @default.
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