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• W2912232459 abstract "Reactions of [Ru(DMF)6]Tf3 with 2- and 5-nitroimidzoles, including the so-called metronidazole (metro), etanidazole (SR2508), and EF5, of known biological value, have been used to synthesize: (a) hydrates of the three new RuII complexes [RuL6]Tf2,(L = 2NO2Im, 5NO2Im), and [Ru(2Me5NO2Im)5]Tf2; and (b) the two new RuIII complexes [Ru(DMF)4(SR2508)2]Tf3 and [Ru(DMF)2(EF5)2(EtOH)2]Tf3. Use of RuCl3٠3H2O as precursor generates hydrates of the complexes: fac- and mer-RuCl3(2NO2Im)3, mer-RuCl3(metro)3, RuCl3(SR2508)2(EtOH), RuCl3(EF5)2(EtOH), and trans-RuCl2(metro)4; a less well characterized complex is formulated RuCl3(2Me5NO2Im)3٠3CO2 containing what appears to be adsorbed CO2." @default.
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• W2912232459 date "2019-04-01" @default.
• W2912232459 modified "2023-09-25" @default.
• W2912232459 title "Syntheses of new ruthenium (II and III)-nitroimidazole complexes" @default.
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• W2912232459 doi "https://doi.org/10.1016/j.ica.2019.01.033" @default.
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