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- W2912233735 endingPage "1439" @default.
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- W2912233735 abstract "A series of new aminophosphonate and phosphonic acid derivatives of hexahydroquinoxalin-2(1H)-ones and tetrahydroquinoxalin-2(1H)-ones were synthesised via hydrophosphonylation of the corresponding bicyclic imines with various dialkyl or diaryl H-phosphonates, H-phosphinates or H-phosphine oxides as phosphorus nucleophiles. The utility of the obtained compounds was demonstrated by their application as a source of phosphonate carbanion in the Horner-Wadsworth-Emmons (HWE) reaction leading to new bicyclic amines with an exocyclic, and unexpectedly, also endocyclic double bond depending on the structure of the aldehyde used." @default.
- W2912233735 created "2019-02-21" @default.
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- W2912233735 date "2019-03-01" @default.
- W2912233735 modified "2023-10-01" @default.
- W2912233735 title "Hydrophosphonylation of chiral hexahydroquinoxalin-2(1H)-one derivatives as an effective route to new bicyclic compounds: Aminophosphonates, enamines and imines" @default.
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- W2912233735 doi "https://doi.org/10.1016/j.tet.2019.01.062" @default.
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