Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912237482> ?p ?o ?g. }
- W2912237482 endingPage "2618" @default.
- W2912237482 startingPage "2607" @default.
- W2912237482 abstract "We have established a method for the highly regio- and enantioselective functionalization of tert-butyl groups via intramolecular amide carbene insertion into C-H bonds, yielding γ-lactams with 91% ee in up to 99% yield. This reaction uses a ruthenium(II) phenyl oxazoline (Ru(II)-Pheox) complex. The catalytic intramolecular carbene transfer reaction to the primary C-H bond proceeds rapidly and selectively compared to that with secondary C-H, benzylic secondary C-H, tert-C-H, or sp2C-H bonds in the presence of 1 mol % Ru(II)-Pheox catalyst. This is the first example of a catalytic carbenoid insertion into an unactivated tert-butyl group with enantiocontrol at the carbenoid carbon." @default.
- W2912237482 created "2019-02-21" @default.
- W2912237482 creator A5043265114 @default.
- W2912237482 creator A5059336877 @default.
- W2912237482 creator A5060270994 @default.
- W2912237482 creator A5077524481 @default.
- W2912237482 creator A5089640612 @default.
- W2912237482 date "2019-01-31" @default.
- W2912237482 modified "2023-10-08" @default.
- W2912237482 title "Regio- and Enantioselective Intramolecular Amide Carbene Insertion into Primary C–H Bonds Using Ru(II)-Pheox Catalyst" @default.
- W2912237482 cites W1975845729 @default.
- W2912237482 cites W1979438000 @default.
- W2912237482 cites W1984232099 @default.
- W2912237482 cites W1992829864 @default.
- W2912237482 cites W1995239729 @default.
- W2912237482 cites W1997498246 @default.
- W2912237482 cites W2013665598 @default.
- W2912237482 cites W2016847480 @default.
- W2912237482 cites W2022821431 @default.
- W2912237482 cites W2025435318 @default.
- W2912237482 cites W2025761037 @default.
- W2912237482 cites W2027513085 @default.
- W2912237482 cites W2029673193 @default.
- W2912237482 cites W2038165172 @default.
- W2912237482 cites W2038352331 @default.
- W2912237482 cites W2050954779 @default.
- W2912237482 cites W2055977866 @default.
- W2912237482 cites W2059325755 @default.
- W2912237482 cites W2064731618 @default.
- W2912237482 cites W2097186155 @default.
- W2912237482 cites W2127409655 @default.
- W2912237482 cites W2160405694 @default.
- W2912237482 cites W2312778188 @default.
- W2912237482 cites W2314599242 @default.
- W2912237482 cites W2327489082 @default.
- W2912237482 cites W2379591351 @default.
- W2912237482 cites W2522311304 @default.
- W2912237482 cites W2593069483 @default.
- W2912237482 cites W2593821341 @default.
- W2912237482 cites W2734740575 @default.
- W2912237482 cites W2766371242 @default.
- W2912237482 cites W2795041309 @default.
- W2912237482 cites W2799808202 @default.
- W2912237482 cites W2830731676 @default.
- W2912237482 cites W2891403535 @default.
- W2912237482 cites W2902911079 @default.
- W2912237482 cites W2903112869 @default.
- W2912237482 cites W2949219049 @default.
- W2912237482 cites W2950300024 @default.
- W2912237482 cites W2950431179 @default.
- W2912237482 cites W2952274737 @default.
- W2912237482 cites W4250113527 @default.
- W2912237482 doi "https://doi.org/10.1021/acs.joc.8b03044" @default.
- W2912237482 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30703331" @default.
- W2912237482 hasPublicationYear "2019" @default.
- W2912237482 type Work @default.
- W2912237482 sameAs 2912237482 @default.
- W2912237482 citedByCount "18" @default.
- W2912237482 countsByYear W29122374822019 @default.
- W2912237482 countsByYear W29122374822020 @default.
- W2912237482 countsByYear W29122374822021 @default.
- W2912237482 countsByYear W29122374822022 @default.
- W2912237482 crossrefType "journal-article" @default.
- W2912237482 hasAuthorship W2912237482A5043265114 @default.
- W2912237482 hasAuthorship W2912237482A5059336877 @default.
- W2912237482 hasAuthorship W2912237482A5060270994 @default.
- W2912237482 hasAuthorship W2912237482A5077524481 @default.
- W2912237482 hasAuthorship W2912237482A5089640612 @default.
- W2912237482 hasConcept C146686406 @default.
- W2912237482 hasConcept C155647269 @default.
- W2912237482 hasConcept C161790260 @default.
- W2912237482 hasConcept C178790620 @default.
- W2912237482 hasConcept C185592680 @default.
- W2912237482 hasConcept C2775944816 @default.
- W2912237482 hasConcept C2776920668 @default.
- W2912237482 hasConcept C2777164566 @default.
- W2912237482 hasConcept C2778439535 @default.
- W2912237482 hasConcept C2779909098 @default.
- W2912237482 hasConcept C521398313 @default.
- W2912237482 hasConcept C555196967 @default.
- W2912237482 hasConcept C71240020 @default.
- W2912237482 hasConcept C75079739 @default.
- W2912237482 hasConceptScore W2912237482C146686406 @default.
- W2912237482 hasConceptScore W2912237482C155647269 @default.
- W2912237482 hasConceptScore W2912237482C161790260 @default.
- W2912237482 hasConceptScore W2912237482C178790620 @default.
- W2912237482 hasConceptScore W2912237482C185592680 @default.
- W2912237482 hasConceptScore W2912237482C2775944816 @default.
- W2912237482 hasConceptScore W2912237482C2776920668 @default.
- W2912237482 hasConceptScore W2912237482C2777164566 @default.
- W2912237482 hasConceptScore W2912237482C2778439535 @default.
- W2912237482 hasConceptScore W2912237482C2779909098 @default.
- W2912237482 hasConceptScore W2912237482C521398313 @default.
- W2912237482 hasConceptScore W2912237482C555196967 @default.
- W2912237482 hasConceptScore W2912237482C71240020 @default.
- W2912237482 hasConceptScore W2912237482C75079739 @default.
- W2912237482 hasFunder F4320334764 @default.
- W2912237482 hasIssue "5" @default.