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- W2912240991 abstract "Wet air oxidation (WAO) is a suitable method for the effective destruction of refinery spent caustic. This work suggests the use of Ruthenium catalyst supported on multi-walled carbon nanotubes (Ru/CNT) for WAO of cresylic spent caustic waste. Using model compounds representative of such waste, such as o-cresol, m-cresol and p-cresol, the suitability of lab-made Ru/CNT (Ru = 5%) for the WAO process was investigated in a slurry reactor. At T = 448 K and PO2 = 100 psi, around 55, 49 and 61% of initial TOC (here TOC denotes total organic carbon) was destroyed within 2 h of reaction with o-cresol, m-cresol and p-cresol. From the TOC vs. time data, kinetic study of TOC reduction for WAO of m-cresol was represented by a hyperbolic Langmuir-Hinshelwood model. Several useful features of the catalyst were examined using electron microscopy, X-ray diffraction and adsorption-desorption of nitrogen. In this way, this work has drawn attention toward this prospective WAO catalyst." @default.
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- W2912240991 date "2019-02-01" @default.
- W2912240991 modified "2023-10-02" @default.
- W2912240991 title "Ruthenium-decorated carbon nanotubes as catalyst for wet air oxidation" @default.
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- W2912240991 doi "https://doi.org/10.1016/j.jece.2019.102914" @default.
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