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- W2912261074 abstract "Measurements of the physical properties of hydrate melts have been made on only a very limited number of systems, mainly because few systems exist in the liquid state at temperatures below 200°C. Such data are needed to test generalized models proposed for electrolyte-water solutions. This paper reports the results of a vapor pressure study on hydrate melts containing a mixture of lithium nitrate and alkali nitrites over the concentration range 0.05–1.7 mol H2O/mol cation at five temperatures between 110° and 150°C. The system is attractive because it exists in the liquid state over the whole range of composition from molten salt to pure water at temperatures above 110°C and is suitable for extending the vapor pressure measurements into the transition region where the electrolyte and water mole fractions are approximately equal. The vapor pressure obeys Henry's Law over the range 0–1 mol H2O/mol cation; the same behavior was observed for hydrate melts containing LiNO3-KNO3. The results are discussed in light of the trends observed for the other hydrate melt systems already studied." @default.
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- W2912261074 date "1984-01-01" @default.
- W2912261074 modified "2023-09-26" @default.
- W2912261074 title "Vapor Pressures of Hydrate Melts Containing Lithium Nitrate and Alkali Nitrites" @default.
- W2912261074 doi "https://doi.org/10.1149/198402.0403pv" @default.
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