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• W2912265400 abstract "Some organic radicals violate the Aufbau principle and have unique electronic structures in which the energy level of the singly occupied molecular orbital (SOMO) is formally lower than that of the highest occupied molecular orbital (HOMO). We synthesized a novel organic radical with a SOMO–HOMO converted electronic structure, TPA-R•, a novel donor–acceptor hybrid of triphenylamine (an electron donor), and a stable polychlorinated diphenyl(4-pyridyl)methyl radical (an electron acceptor). TPA-R• exhibited fluorescence in the near-infrared region (λmax = 910 nm) in cyclohexane from a polar intramolecular charge-transfer excited state. Cyclic voltammetry, absorption spectroscopy, and density functional theory calculation revealed the inversion of the SOMO and HOMO levels in the electronic structure of TPA-R•. Addition of trifluoromethanesulfonic acid to TPA-R• caused a two-step change. Protonation initially occurred on the diphenylpyridylmethyl radical moiety to form TPA-[RH]•+. This protonation induced larg..." @default.
• W2912265400 created "2019-02-21" @default.
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• W2912265400 date "2019-02-08" @default.
• W2912265400 modified "2023-10-17" @default.
• W2912265400 title "NIR Emission and Acid-Induced Intramolecular Electron Transfer Derived from a SOMO–HOMO Converted Non-Aufbau Electronic Structure" @default.
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• W2912265400 doi "https://doi.org/10.1021/acs.jpcc.8b08574" @default.
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