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- W2912266091 endingPage "3375" @default.
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- W2912266091 abstract "Molecular dynamic crystals conveniently combine flexibility required for mechanical reconfiguration, strength for effective translation of elastic energy, and long-range order of mechanically coupled molecules for rapid conversion of disordered motion (heat) or photons (light) into ordered motion (work). By direct measurement of the actuation force generated by crystals of a thermosalient solid, here we describe the first direct quantification of the work performed and energy conversion that can be accomplished by using dynamic crystals as supramolecular actuators. Upon reversible α-to-γ phase transition, crystals of (phenylazophenyl)palladium hexafluoroacetylacetonate of submillimeter to millimeter size exert forces in the range of 1-100 mN upon longitudinal and lateral expansion. This work translates to a volumetric power density of about 1-3 MW m-3 and efficiency comparable to the existing multicomponent actuators." @default.
- W2912266091 created "2019-02-21" @default.
- W2912266091 creator A5001482734 @default.
- W2912266091 creator A5003363499 @default.
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- W2912266091 date "2019-02-11" @default.
- W2912266091 modified "2023-10-05" @default.
- W2912266091 title "Direct Quantification of Rapid and Efficient Single-Stroke Actuation by a Martensitic Transition in a Thermosalient Crystal" @default.
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- W2912266091 doi "https://doi.org/10.1021/jacs.8b12752" @default.
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