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- W2912269446 abstract "Abstract Utilizing two uncommon organic ligands with different flexible linkers, 4,4′-bis(1H-benzotriazoloxymethyl)pentane (L1) and 4,4′-bis(1H-benzotriazoloxymethyl) hexane (L2), two novel Anderson polyoxometalate-based metal–organic networks with different structures, {Cu2(L1)2[CrMo6(OH)5O19]}·2H2O·2C2H5OH (1), {Cu3(L2)2[CrMo6(OH)6O18]2(H2O)4}·10H2O (2), have been constructed under solvothermal condition and characterized by IR spectra, single crystal X-ray diffraction and powder X-ray diffraction. The 2D network of complex 1 is constructed from inorganic {Cu-CrMo6} chains and L1 ligands. Complex 2 exhibits a 3D framework with {424, 64} topology, where the coordination between CrMo6 anions and CuII ions give a 2D inorganic layer, further extended into a 3D framework by L2 ligands. The influence of solvents on the synthesis of title complexes was investigated, and the effect of ligand spacer length on the structures of the title complexes was discussed. Two complexes display not only electrocatalytic activities toward the reduction of H2O2 and KNO2, but also good adsorption activities for organic dye crystal violet (CV) and methylene blue (MB)." @default.
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- W2912269446 date "2019-04-01" @default.
- W2912269446 modified "2023-10-17" @default.
- W2912269446 title "Solvent-directed Anderson-type polyoxometalate-based metal–organic networks with flexible bis(1H-benzotriazoloxymethyl) ligands" @default.
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- W2912269446 doi "https://doi.org/10.1016/j.poly.2019.01.066" @default.
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