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- W2912270563 abstract "Abstract Similar atom substitution is an effective strategy to develop (La Ce) Al-(Ni Co) bulk metallic glasses (BMGs) with high glass forming ability (GFA). But the effect of similar element substitution on GFA has not been clarified. In this paper, the effect of similar atom substitution (Co and Ce) on the GFA of La62Al14Ni24 ternary alloy has been studied based on the concept of Fermi sphere - Brillouin zone interaction. The effect of Co atom substitution is primarily on the electron hybridization between Al atoms and Ni (Co) atoms, affecting the diameter of the Fermi sphere (2KF), and that of Ce atom substitution is mainly a change in the diameter of the pseudo-Brillouin zone (KP). And their effects on the Fermi level and Brillouin zone size are monitored using spectroscopy experiments. The |δ| = | KP -2KF | criterion was used to evaluate this similar atom substitution effect, which guides us to predict the influence trend of similar atom substitution (Co and Ce) on the GFA in the La Al Ni ternary alloy system and was confirmed by the experimental results." @default.
- W2912270563 created "2019-02-21" @default.
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- W2912270563 date "2019-05-01" @default.
- W2912270563 modified "2023-10-16" @default.
- W2912270563 title "Similar atom substitution effect on the glass forming ability in (La Ce) Al-(Ni Co) bulk metallic glasses using electron structure guiding" @default.
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- W2912270563 doi "https://doi.org/10.1016/j.jallcom.2019.01.339" @default.
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