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- W2912272069 abstract "This communication details the first total synthesis of the 13-membered macrolide, (−)-Melearoride A, as well as unnatural (+)-Melearoride A. The synthesis features a concise 13 step synthesis (11 steps longest linear sequence) that offers flexible stereo-control and multiple opportunities for unnatural analog synthesis to delve into antifungal SAR. The route features a cuprate addition, an Evans asymmetric alkylation, and a ring-closing metathesis (RCM) to close the 13-membered macrocyclic core." @default.
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- W2912272069 date "2019-03-01" @default.
- W2912272069 modified "2023-10-16" @default.
- W2912272069 title "Total synthesis of natural (−)- and unnatural (+)-Melearoride A" @default.
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- W2912272069 doi "https://doi.org/10.1016/j.tetlet.2019.02.006" @default.
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