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- W2912277674 abstract "Several of the rhodium-catalyzed indolizations are equally accomplished with ruthenium. An example is the deoxygenation of 2-nitrostilbene to 2-phenylindole with Ru3(CO)12. The use of ruthenium to construct indoles may have been first reported by Watanabe and colleagues, and followed up by Izumi and Yokota. In the latter study, the Ru catalyst was superior to Pd(OAc)2. Tokunaga and Wakatsuki reported a one-pot indole synthesis from anilines and propargyl alcohols using Ru3(CO)12, and Nicholas and colleagues reported a Ru-catalyzed indole synthesis via the reductive annulation of nitrosoarenes with alkynes. Saa and coworkers described the Ru-catalyzed cycloisomerization of o-alkynylanilines. Jia and Driver both discovered a Ru-catalyzed intramolecular amination of aryl azides to give indoles, carbazoles, and carbolines, including a synthesis of the γ-carboline alkaloid dimebolin. An effective use of ruthenium was ring-closing metathesis with the two ruthenium-containing Grubbs catalysts." @default.
- W2912277674 created "2019-02-21" @default.
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- W2912277674 date "2016-06-17" @default.
- W2912277674 modified "2023-10-18" @default.
- W2912277674 title "Ruthenium‐Catalyzed Indole Ring Synthesis" @default.
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- W2912277674 doi "https://doi.org/10.1002/9781118695692.ch82" @default.
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