Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912309999> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2912309999 endingPage "945" @default.
- W2912309999 startingPage "937" @default.
- W2912309999 abstract "The new carbon electrodes containing alkali metal fluorides such as LiF-CaF2 and CaF2 were developed to prevent the occurrence of anode effect in electrochemical fluorination and were used as the anode for electrolytic synthesis of perfluorotrimethylamine, (CF3)3N, from the mixed melt of (CH3)4NF · 5HF and KF · 2HF at 100°C. The ratio of (CF3)3N to the overall anode gas increased with increasing the concentration of (CH3)4NF and decreasing the current density and the best value of 61.7% was obtained in electrolysis of the mixed melt of (CH3)4NF · 5HF (40 mol%) and KF · 2HF (60 mol%) at 20 mA · cm−2 with the 4 wt% CaF2 contained carbon anode. However, the new carbon anode was broken down in the mixed melt of (CH3)4NF · 5HF (50 mol%) and KF · 2HF (50mol%) during electrolysis. From these results, it is concluded that the alkali fluoride contained carbon is available as the anode for electrolytic production of (CF3)3N from the mixed melt having the molar fraction of KF higher than 0.143." @default.
- W2912309999 created "2019-02-21" @default.
- W2912309999 creator A5008486667 @default.
- W2912309999 date "2002-01-01" @default.
- W2912309999 modified "2023-09-26" @default.
- W2912309999 title "Electrolytic Synthesis of Perfluorotrimethylamine with Alkali Metal Fluroide Contained Carbon Anode" @default.
- W2912309999 doi "https://doi.org/10.1149/200219.0937pv" @default.
- W2912309999 hasPublicationYear "2002" @default.
- W2912309999 type Work @default.
- W2912309999 sameAs 2912309999 @default.
- W2912309999 citedByCount "0" @default.
- W2912309999 crossrefType "journal-article" @default.
- W2912309999 hasAuthorship W2912309999A5008486667 @default.
- W2912309999 hasBestOaLocation W29123099991 @default.
- W2912309999 hasConcept C104779481 @default.
- W2912309999 hasConcept C140205800 @default.
- W2912309999 hasConcept C147789679 @default.
- W2912309999 hasConcept C159985019 @default.
- W2912309999 hasConcept C163127949 @default.
- W2912309999 hasConcept C17525397 @default.
- W2912309999 hasConcept C178790620 @default.
- W2912309999 hasConcept C179104552 @default.
- W2912309999 hasConcept C185592680 @default.
- W2912309999 hasConcept C192562407 @default.
- W2912309999 hasConcept C198091228 @default.
- W2912309999 hasConcept C2780828025 @default.
- W2912309999 hasConcept C52859227 @default.
- W2912309999 hasConcept C68801617 @default.
- W2912309999 hasConcept C89395315 @default.
- W2912309999 hasConceptScore W2912309999C104779481 @default.
- W2912309999 hasConceptScore W2912309999C140205800 @default.
- W2912309999 hasConceptScore W2912309999C147789679 @default.
- W2912309999 hasConceptScore W2912309999C159985019 @default.
- W2912309999 hasConceptScore W2912309999C163127949 @default.
- W2912309999 hasConceptScore W2912309999C17525397 @default.
- W2912309999 hasConceptScore W2912309999C178790620 @default.
- W2912309999 hasConceptScore W2912309999C179104552 @default.
- W2912309999 hasConceptScore W2912309999C185592680 @default.
- W2912309999 hasConceptScore W2912309999C192562407 @default.
- W2912309999 hasConceptScore W2912309999C198091228 @default.
- W2912309999 hasConceptScore W2912309999C2780828025 @default.
- W2912309999 hasConceptScore W2912309999C52859227 @default.
- W2912309999 hasConceptScore W2912309999C68801617 @default.
- W2912309999 hasConceptScore W2912309999C89395315 @default.
- W2912309999 hasIssue "1" @default.
- W2912309999 hasLocation W29123099991 @default.
- W2912309999 hasOpenAccess W2912309999 @default.
- W2912309999 hasPrimaryLocation W29123099991 @default.
- W2912309999 hasRelatedWork W1538560499 @default.
- W2912309999 hasRelatedWork W1822384015 @default.
- W2912309999 hasRelatedWork W2056943440 @default.
- W2912309999 hasRelatedWork W2387133619 @default.
- W2912309999 hasRelatedWork W4200588494 @default.
- W2912309999 hasRelatedWork W4280539846 @default.
- W2912309999 hasRelatedWork W4281477020 @default.
- W2912309999 hasRelatedWork W4285248643 @default.
- W2912309999 hasRelatedWork W4310623197 @default.
- W2912309999 hasRelatedWork W572968396 @default.
- W2912309999 hasVolume "2002-19" @default.
- W2912309999 isParatext "false" @default.
- W2912309999 isRetracted "false" @default.
- W2912309999 magId "2912309999" @default.
- W2912309999 workType "article" @default.