Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912311246> ?p ?o ?g. }
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- W2912311246 startingPage "61" @default.
- W2912311246 abstract "Group 14 metal-containing linear polymers (E = Ge, Sn), which are structurally analogous to saturated polymeric hydrocarbons and polysilanes, can be approximated as linear chains of EE single bonds allowing for a covalently linked (semi)-metal backbone, [R2E] n . In contrast to saturated polymeric hydrocarbons, group 14 metal-containing linear polymers have the capacity to catenate. Heavier germanium and tin atoms in the backbone of σ-conjugated polymers are expected to give stronger σ-conjugation, narrower bandgaps, and induce more metallic character to the resulting material as compared to their silicon counterparts and can be described as molecular wires embedded in an organic jacket. With the rising interest in these materials in the field of electronics, this chapter will present the preparation of stable group 14 metal-containing linear polymers, focusing on group 14 metal hydrides (R n EH4−n ) as building blocks. In addition, the application of alternative group 14 metal hydride precursors, namely group 14 metal trihydrides REH3, toward the preparation of novel group 14 metal polymeric networks is presented." @default.
- W2912311246 created "2019-02-21" @default.
- W2912311246 creator A5016432225 @default.
- W2912311246 creator A5025789862 @default.
- W2912311246 creator A5083296313 @default.
- W2912311246 date "2019-02-01" @default.
- W2912311246 modified "2023-09-25" @default.
- W2912311246 title "Synthesis of Group 14 Metal‐ <scp>C</scp> ontaining Polymers" @default.
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