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• W2912331817 abstract "Abstract Alkenylpyridines are important pharmaceutical cores as well as versatile building blocks in organic synthesis. Heck reaction represents one of the most powerful platform for the construction of aryl-substituted alkenes, nevertheless, examples for Heck type coupling of alkenes with pyridines, particularly with branched selectivity, remain elusive. Here we report a catalytic, branch-selective pyridylation of alkenes via a sulfinate assisted photoredox catalysis. This reaction proceeds through a sequential radical addition/coupling/elimination, by utilizing readily available sodium sulfinates as reusable radical precursors as well as traceless elimination groups. This versatile protocol allows for the installation of important vinylpyridines with complete branched selectivity under mild conditions. Furthermore, this catalytic manifold is successfully applied to the expedient synthesis of Triprolidine." @default.
• W2912331817 created "2019-02-21" @default.
• W2912331817 creator A5000185870 @default.
• W2912331817 creator A5001014826 @default.
• W2912331817 creator A5002661071 @default.
• W2912331817 creator A5028147598 @default.
• W2912331817 creator A5088919139 @default.
• W2912331817 date "2019-02-14" @default.
• W2912331817 modified "2023-10-16" @default.
• W2912331817 title "Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine" @default.
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• W2912331817 doi "https://doi.org/10.1038/s41467-019-08669-1" @default.
• W2912331817 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6375965" @default.
• W2912331817 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30765695" @default.
• W2912331817 hasPublicationYear "2019" @default.
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• W2912331817 hasAuthorship W2912331817A5000185870 @default.
• W2912331817 hasAuthorship W2912331817A5001014826 @default.
• W2912331817 hasAuthorship W2912331817A5002661071 @default.
• W2912331817 hasAuthorship W2912331817A5028147598 @default.
• W2912331817 hasAuthorship W2912331817A5088919139 @default.

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