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- W2912332897 abstract "N-nitrosamines, as a class of compounds, have been reported to be mutagenic, cytotoxic, genotoxic and carcinogenic. N-nitrosamine formation and emission are a major concern for amine-based CO2 capture systems. A process using a stationary carbon electrode inside an electrochemical cell was developed and tested in this study to adsorb and decompose two N-nitrosamines, N-nitrosopyrrolidine and N-nitrosodiethylamine, from an aqueous amine solution. The carbon xerogel electrode material has a high N-nitrosamine adsorption capacity and can initiate an electrochemically-mediated reduction of N-nitrosamines to a secondary amine. A greater than 80% reduction of N-nitrosodiethylamine and 90% of N-nitrosopyrrolidine was observed from a simulated amine-based waterwash solution using an applied current up to 300 mA. N-nitrosamine decomposition was effective in solutions with relatively high amine or salt concentrations." @default.
- W2912332897 created "2019-02-21" @default.
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- W2912332897 date "2019-04-01" @default.
- W2912332897 modified "2023-09-23" @default.
- W2912332897 title "Decomposition of N-nitrosamines formed in CO2 capture systems through electrochemically-mediated reduction on carbon xerogel electrode" @default.
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- W2912332897 doi "https://doi.org/10.1016/j.ijggc.2019.02.003" @default.
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