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• W2912334056 startingPage "108148" @default.
• W2912334056 abstract "The electronic structure of mineral tetrahedrite Cu12Sb4S13 showing a metal-semiconductor transition (MST) at TMST = 85 K has been investigated by means of Cu 1s x-ray absorption spectroscopy with the partial fluorescence yield mode (PFY-XAS) and Cu 2p-1s x-ray emission spectroscopy (XES). Remarkable changes are detected in both the PFY-XAS and XES spectra on cooling across TMST. The changes in the spectra indicate that the unoccupied Cu 3d and 4p densities of states (DOS) shift away from the Fermi energy (EF). We conclude that the MST of Cu12Sb4S13 is associated with the decrease of the Cu 3d DOS at EF." @default.
• W2912334056 created "2019-02-21" @default.
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• W2912334056 date "2020-10-01" @default.
• W2912334056 modified "2023-10-18" @default.
• W2912334056 title "Cu 2p-1s x-ray emission spectroscopy of mineral tetrahedrite Cu12Sb4S13" @default.
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• W2912334056 doi "https://doi.org/10.1016/j.radphyschem.2019.02.007" @default.
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