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- W2912338415 abstract "Ruthenium (II) metallodendrimer (RuDen) and the wheel-shaped Cu20-Tungstophosphate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25− heteropolyanion (HPA) were successfully immobilised on a glassy carbon electrode through employment of the Layer-by-Layer (LBL) deposition method. The fabricated (Cu20P8W48/RuDen) multilayer films have been investigated with cyclic voltammetry, electrochemical impedance spectroscopy (EIS) and surface based techniques. The layers exhibited well behaved redox activity for both the HPA and RuDen moieties and exhibited good stability towards redox cycling and associated thin layer behaviour. The charge transfer resistance (Rct) and Warburg Impedance (Zw) obtained values for the layers by EIS indicated an increase the compactness of the layers upon construction. The (Cu20P8W48/RuDen) multilayer films exhibited electrocatalytic ability towards the reduction of iodate." @default.
- W2912338415 created "2019-02-21" @default.
- W2912338415 creator A5064036615 @default.
- W2912338415 creator A5064948815 @default.
- W2912338415 creator A5070884948 @default.
- W2912338415 creator A5090569594 @default.
- W2912338415 date "2019-03-01" @default.
- W2912338415 modified "2023-09-26" @default.
- W2912338415 title "Electrochemical, surface and electrocatalytic properties of electrode multilayer assemblies composed of a ruthenium metallodendrimer and a wheel-shaped Cu-20 Tungstophosphate" @default.
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- W2912338415 doi "https://doi.org/10.1016/j.jelechem.2019.01.047" @default.
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