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• W2912358429 endingPage "149" @default.
• W2912358429 startingPage "141" @default.
• W2912358429 abstract "Coordination polymers constructed from conjugated organic ligands and metal ions with a d 10 electronic configuration exhibit intriguing properties for chemical sensing and photochemistry. A Zn II -based coordination polymer, namely poly[aqua(μ 6 -biphenyl-3,3′,5,5′-tetracarboxylato)(μ 2 -4,4′-bipyridine)dizinc(II)], [Zn 2 (C 16 H 6 O 8 )(C 10 H 8 N 2 )(H 2 O) 2 ] n or [Zn 2 ( m , m -bpta)(4,4′-bipy)(H 2 O) 2 ] n , was synthesized from a mixture of biphenyl-3,3′,5,5′-tetracarboxylic acid [H 4 ( m , m -bpta)], 4,4′-bipyridine (4,4′-bipy) and Zn(NO 3 ) 2 ·6H 2 O under solvothermal conditions. The title complex has been structurally characterized by IR spectroscopy, elemental analysis, single-crystal X-ray diffraction and powder X-ray diffraction analysis, and features a μ 6 -coordination mode. The Zn II ions adopt square-pyramidal geometries and are bridged by two syn – syn carboxylate groups to form [Zn 2 (COO) 2 ] secondary buildding units (SBUs). The SBUs are crosslinked by ( m , m -bpta) 4− ligands to produce a two-dimensional grid-like layer that exhibits a stair-like structure along the a axis. Adjacent layers are linked by 4,4′-bipy ligands to form a three-dimensional network with a {4 4 .6 10 .8}{4 4 .6 2 } topology. In the solid state, the complex displays a strong photoluminescence and an excellent solvent stability. In addition, the luminescence sensing results indicate a highly selective and sensitive sensing for Fe 3+ ions." @default.
• W2912358429 created "2019-02-21" @default.
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• W2912358429 date "2019-01-23" @default.
• W2912358429 modified "2023-10-12" @default.
• W2912358429 title "Synthesis, structure and selective luminescence sensing for iron(III) ions of a three-dimensional zinc(II) (4,6)-connected coordination network" @default.
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• W2912358429 doi "https://doi.org/10.1107/s2053229619000767" @default.
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