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- W2912374354 abstract "We synthesized micrometer-sized LiCoMnO4 with spinel structure by heating ion-exchanged LixCo0.5Mn0.5O2 with O6-type layered rocksalt structure at 600 °C. In this synthetic route, we first synthesized micrometer-sized NaxCo0.5Mn0.5O2 with P2-type layered rocksalt structure at 900 °C. Then, we prepared O6-LixCo0.5Mn0.5O2 by ion-exchange of Na+ for Li+ using LiNO3 at 280 °C. The structural transformation from layered rocksalt to spinel structure was confirmed at about 600 °C by the DTA curve. The average particle size of about 5 μm was almost the same as that of the starting P2-NaxCo0.5Mn0.5O2. The discharge capacity–voltage curves of the present LiCoMnO4 showed a maximum discharge capacity of about 105 mA h g−1 between 3.0 and 5.2 V vs. Li/Li+ at 25 °C, in spite of large micrometer-sized particles. We believe that micrometer-sized LiCoMnO4 would be important as one of 5 V cathode materials to achieve its higher compressed density of the electrode for advanced lithium ion batteries (LIBs), such as all solid-state LIB application." @default.
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- W2912374354 date "2019-05-01" @default.
- W2912374354 modified "2023-10-18" @default.
- W2912374354 title "A novel synthetic route of micrometer-sized LiCoMnO4 as 5 V cathode material for advanced lithium ion batteries" @default.
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- W2912374354 doi "https://doi.org/10.1016/j.ssi.2018.12.024" @default.
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