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• W2912378201 abstract "We report in this communication the synthesis, structure, and magnetic investigations of two new half-sandwich complexes: [Dy(DAD)Cp*(THF)] (1) and [Li(THF)3][Dy(DAD)Cp*Cl] (2) (Cp*: C5Me5, DAD: [2,6-iPr2C6H3N–CMe=CMe–NC6H3iPr2–2,6). Both compounds exhibit zero-field single-molecule magnet behavior but distinct relaxation dynamics originating from difference in the arrangement of Cp* and DAD ligands. The anisotropic barrier for 1 is found to be 1 order of magnitude greater than for 2." @default.
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• W2912378201 date "2019-02-04" @default.
• W2912378201 modified "2023-10-13" @default.
• W2912378201 title "Single-Molecule Magnet Behavior in Dy³⁺ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands" @default.
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• W2912378201 doi "https://doi.org/10.1021/acs.organomet.8b00901" @default.
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