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- W2912394101 abstract "A simple and efficient synthetic route for preparing the benzonaphthyridine framework is reported. Only seven steps are needed for the assembly of 3-alkylamino aaptamine from inexpensive isoquinoline 6 by this route with about 20% overall yield. The two key steps are a novel palladium-catalyzed reductive cyclization with Mo(CO)6 as reductant to form aaptamine and demethyloxyaaptamine and a hydrogen-bond-mediated oxidative alkylamination to account for the complete regioselectivity." @default.
- W2912394101 created "2019-02-21" @default.
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- W2912394101 date "2019-02-18" @default.
- W2912394101 modified "2023-10-16" @default.
- W2912394101 title "Total Synthesis of Aaptamine, Demethyloxyaaptamine, and Their 3-Alkylamino Derivatives" @default.
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- W2912394101 doi "https://doi.org/10.1021/acs.orglett.9b00183" @default.
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