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- W2912394171 abstract "The synthesis of a crystalline ethynyl-1,2-benziodoxol-3(1 H)-one (EBX)-acetonitrile complex is described. EBX has been widely used as an active species for a variety of reactions; however, its high instability has so far prevented its isolation. The EBX-acetonitrile is self-assembled into a double-layered honeycomb structure through weak hypervalent iodine secondary interactions and hydrogen bonding. The N-ethynylation of a variety of sulfonamides using the EBX-acetonitrile complex as a substrate under mild conditions is also described." @default.
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- W2912394171 date "2019-02-01" @default.
- W2912394171 modified "2023-10-01" @default.
- W2912394171 title "Synthesis, Characterization, and Reactivity of an Ethynyl Benziodoxolone (EBX)–Acetonitrile Complex" @default.
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- W2912394171 doi "https://doi.org/10.1021/acs.orglett.9b00005" @default.
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